Hyperbolic models in gas-solid chromatography
نویسندگان
چکیده
We present different models arising in chemical engineering and essentially related to isothermal gas chromatography. These models describe a fixed bed adsorption process of separation of a gaseous mixture: each compound can exist either in a mobile phase or a solid and static one, with a finite or infinite mass-exchange kinetics. Many authors, in the fields of chemical engineering and mathematics, have investigated these models under various assumptions, from a theoretical or numerical point of view. We explain first the relations between some of these approaches. Next, we present some results related to these models, some of them being new, particularly in the case of a monovariant system with one or two active compounds for the Cauchy problem. Lastly, we mention some open problems.
منابع مشابه
Comparison of the hyperbolic range of two-fluid models on two-phase gas -liquid flows
In this paper, a numerical study is conducted in order to compare hyperbolic range of equations of isotherm two-fluid model governing on two-phase flow inside of pipe using conservative Shock capturing method. Differential equations of the two-fluid model are presented in two forms (i.e. form I and form II). In forms I and II, pressure correction terms are hydrodynamic and hydrostatic, respecti...
متن کاملKinetic formulation of a 2 2 hyperbolic system arising in gas chromatography
The PSA system commonly used in the context of gas-solid chromatography is reformulated as a single kinetic equation using an additional kinetic variable. A kinetic numerical scheme is built from this new formulation and its behavior is tested on solving the Riemann problem in different configurations leading to single or composite waves.
متن کاملMultiresidue determination of organophosphorus pesticides in corn oil using solid-phase extraction with lanthanum silicate sorbent and gas chromatography
Phosalone, malathion and diazinon were analyzed in corn oil using solid phase extraction (SPE)with lanthanum silicate as a new solid sorbent followed by gas chromatography with nitrogenphosphorus detection (GC-NPD). The efficiency of different eluents (methanol, dichloromethane,ethyl acetate, dichloromethane — ethyl acetate (1:1) and ethyl acetate — methanol (1:1)) werecompared for elution of o...
متن کاملEulerian and Lagrangian formulations in BV s for gas-solid chromatography
–An initial-boundary value problem for a chemical system with unknown velocity related to gas chromatography is considered. The system is hyperbolic and existence of entropy solutions is achieved in fractional BV spaces: BV , s ≥ 1/3, with less regularity than usual. We prove that BV 1/3 is the critical space for this problem. A Lagrangian formulation of the system for the initial value problem...
متن کاملStrong Stability with respect to weak limit for a Hyperbolic System arising from Gas Chromatography
We investigate a system related to a particular isothermal gas-solid chromatography process, called “Pressure Swing Adsorption”, with two species and instantaneous exchange kinetics. This system presents the particularity to have a linearly degenerate eigenvalue: this allows the velocity of the gaseous mixture to propagate high frequency waves. In case of smooth concentrations with a general is...
متن کامل